Research

Strontium-Ruthenate and Strontium-Rhodium Compounds


Initially, strontium-ruthenate compounds were thought relatable to the high-Tc superconductors—both kinds of material are highly two-dimensional (2D), and the crystal structure of Sr2RuO4 is almost identical to that of the (La, Sr)2CuO4 superconductors. Furthermore, both materials are oxides with conduction occurring in partially filled d-bands (of the strontium or copper ions) that are strongly hybridized with the oxygen ions' p orbitals. Yet, in Sr2RuO4, superconductivity appears only at low temperatures (1.5K), in samples with very low residual resistivity, and out of a normal state that is a well-formed Landau-Fermi liquid putting them in a different regime than high-Tc superconductors. ARPES investigations concentrated on providing evidence for the prototypical Fermi liquid nature of the strontium-ruthenate compounds, and mapping the rich band structure in this complex material, in remarkable agreement with de Haas-van Alphen quantum oscillation measurements. Strontium-Rhodium compounds also allow a clean mapping of the band structure and exhibit strong Fermi-liquid behavior, a great testing ground for theory.